I saw these pieces at Pottery Barn and took a pic so I could see about replicating them. The Barn sells them painted, in gloss white or gloss black.
Shown here from my Sketchup model, which is not complete with all the details and joinery, but is complete enough to see what needs to happen, build-wise.
I thought the desk top might be best done using 3/4 MDF, edged four sides in hardwood. For the box case of the file cabinet, a mix of 12mm and 19mm baltic birch plywood. Same for drawerboxes in the desk. All else done using something like yellow poplar, for its paintability.
Taper jigs will be built for ripping the skewed faces of the legs, and some routing and careful trimming will be done for the various leg mortises.
Please comment on my choices of materials. I would like alternatives if they might work better.