I have recently been laser engraving a large job of 600 ID door plates for a couple of apartment complexes that I am doing signs for. These plates are made of 1/4" melamine (cut out with cnc router), engraved in the laser and paint filled. I started out masking them with application tape, engraving them, paint filling and then removing the mask. The problem was that the paint would wick into the paper tape and then the edges of the letters would not be sharp.
I found a product sold by my plastics supplier, Piedmont Plastics Corp, called Pflex. It is a polyester film with an adhesive back. It costs $2.00 or so for a 36" x 24" custom cut sheet. I have a jig made for the laser table that holds 24 of the plates. I cover the whole thing with the polyester film, engrave the plates,( which disentegrates the film), spray paint and remover the mask to the crisp edge letters. We used it this week to make some aluminum signs for use at the swimming pool. Covered them, kiss cut the polyester mask, weeded it out then spray painted it. Worked like a charm.