True, but the reason we use two out-of-phase 120V lines to generate 240V is because it minimizes any additional danger that might be present when dealing with a higher voltage. You can touch either leg and only "see" 120V to ground. Thus, unless you happen to touch both hot legs at the same time (awfully unlikely, if you are being even remotely careful), the statement I made earlier ("there is nothing MORE difficult or dangerous about it") is true. I point this out because too many people seem to think that 120V wiring is something they would readily tackle, but 240V is "scary", when in fact, they are almost exactly the same.
As George points out, many (most?) jurisdictions allow a homeowner to do electrical work within their own residence without permit or inspection. He's just adding a few outlets - what would there be to inspect? Make sure all the screws are tight, and you used the right gauge wire, and....? Anything else? I can't think of anything.