Another way is to cut them at 45° and then increase the angle on a 45° bevel shooting board. Same idea as Wayne's, put a shim under the outside end of the molding to get the angle you want, then a few strokes with the plane and you will have the exact angle you want and the cut will be as good or better than any other way of doing it. And since you are making a higher angle you can cut your initial 45's at final length, if desired.
John