Hi T.J.,
For 5" pipe you can use HVAC snaplock pipe (28ga-26ga should be fine) or 5" spiral pipe. I'm using a combo of snaplock and spiral in my shop depending on the application. Snaplock from the Borg (28ga in 30" lengths in my area) and spiral from a local distributor. I went to an HVAC/plumbing supply place and asked them for spiral pipe. They referred me to a local distributor. Spiral is sold in 10' lengths so bring a vehicle that can carry it. Your local distributor might not be interested in cutting it for you.
For fittings I'm using 28ga HVAC pieces from the Borg. Works for me.
Cheers,
Allan