Now, put a 45 degree drafting triange against the blade plate and against the miter gauge face and set it to 45 degrees.
To make and accurate picture frame you must start with a two pairs of boards of exactly the same width and each pair must be exactly the same length. You should be cutting the boards to length as you cut the miter. Use a stop block on your miter gauge. Fit the pieces together and if they don't fit, slightly adjust the miter gauge angle to correct.
Finally, for picture frames it is much preferred that you use a crosscut sled so you don't have to adjust your miter gauge. Cuts are much more accurate and repeatable.