James,
Far as figuring volume if more a less an educated guess. I have done it so much that I am rarely more than 4 or 5 oz. off. I use to mathematically figure the volume of the form and the piece as close as possible. Now I have extra resin and pigments ready to mix just in case I do not have enough to fill the form.
Pressure is a sensitive subject and the pressures I use are not for the faint of heart. I never suggest that anyone uses my methods and I will just say the pressures I use are significantly higher than what you are using or that any pots are rated for.
Good Luck
Alan